Material selection

Material selection is an optimization process. Material selection shall be optimized, considering capital cost and operational costs, and minimizing the overall Life Cycle Costs while providing acceptable levels of safety and reliability. The following key factors apply to materials selection:

  • Easy availability of materials
  • Suitability for the design life taking into consideration the corrosion allowance
  • Compatibility of material with the process fluid
  • Suitability of the material for the design temperature and pressure and cyclic loading
  • Suitability of materials for the environmental conditions (e.g saline corrosive environment may render some materials ineffective though the material may be compatible with the process fluid)
  • Potential ultraviolet degradation of the materials
  • Feasibility of providing economical supporting arrangement
  • Past experience with material for similar applications
  • Additional requirements for corrosion protection such as cathodic protection, chemical injection, inspection, corrosion monitoring and any environmental impact due their implementation
  • Weight reduction.
  • Fabrication, Inspection and Installation Costs
  • Evaluation of failure probabilities, failure modes and consequences

Approach to Material Selection

The sequence of material selection depicted below applies predominantly to oil and gas industry. The basis of material selection uses progressively more expensive material options and is as follows:

  1. Use bare carbon steel material i.e. without any internal coating with a corrosion allowance.
  2. Use bare carbon steel with corrosion inhibition.
  3. Use carbon steel pipe with internal coating or lining.
  4. Use carbon steel with cathodic protection.
  5. Use Corrosion Resistant Alloy (CRA).

Both metallic and non-metallic materials are used in piping systems. Metallic materials can be classified into two broad categories:

  • Ferrous Piping
    • Carbon Steel
    • Stainless Steel
    • Duplex Steel
    • Cast Iron
    • Ductile Iron
  • Non-Ferrous Piping
    • Copper
    • Copper Nickel
    • Inconel 625
    • Titanium
    • Aluminium

Carbon and low alloy steels are routinely specified for chemical, petrochemical, paper, oil production and gas processing equipment for sweet and sour service provided the general and pitting corrosion can be maintained within acceptable bounds and the materials are resistant to sulfide stress cracking. Carbon steel with adequate corrosion allowance is suitable for many applications and performs satisfactorily at temperatures between -29°C and 427°C. If the predicted corrosion rates of carbon steel are not sustainable for the design life of the plant facilities considering an acceptable corrosion allowance, an active means of protection of carbon steel must be considered. In most cases a corrosion allowance of 3 mm is considered appropriate to meet the design life for carbon steel material. In many engineering organizations a 6 mm corrosion allowance is considered as the upper limit of corrosion allowance.

Low-temperature carbon steel is used for subzero temperatures and low-alloy carbon steel is used for high temperature applications. After carbon steel, stainless steel can be used for many corrosive service applications followed by duplex steels and other corrosion resistant alloys such as Inconel 625 and Incoloy 825. Metallurgist or Corrosion Engineer is in most organizations responsible for preparation of material selection philosophy, material selection report and material selection diagrams. The material selection report and material selection diagram forms the basis for developing the piping material classes. 

ASME B31.3 lists the commonly used metallic piping materials. Table below lists the various ASTM codes for Ferrrous and Non-Ferrous materials used in plant facilities.

List of ASTM Codes for Piping Materials - Ferrous Materials

ASTM Grade Material Description
A48 Standard Specification for Gray Iron Castings
A53 Standard Specification for Pipe, Steel, Black and Hot-Dipped, Zinc Coated, Welded and Seamless
A105 Standard Specification for Forgings, Carbon Steel, For Piping Components
A106 Standard Specification for Seamless Carbon Steel Pipe For High-Temperature Service
A126 Standard Specification for Gray Cast Iron Castings For Valves, Flanges, and Pipe Fittings
A134 Standard Specification for Pipe, Steel, Electric-Fusion (Arc)-Welded (Sizes Nps 16 and Over)
A135 Standard Specification for Electric-Resistance-Welded Steel Pipe
A139 Standard Specification for Electric-Fusion (Arc)-Welded Steel Pipe (Nps 4 and Over)
A167 Standard Specification for Stainless and Heat-Resisting Chromium-Nickel Steel Plate, Sheet and Strip
A179 Standard Specification for Seamless Cold-Drawn Low-Carbon Steel Heat- Exchanger and Condenser Tubes
A181 Standard Specification for Forgings, Carbon Steel For General Purpose Piping
A182 Standard Specification for Forged Or Rolled Alloy-Steel Pipe Flanges, Forged Fittings, and Valves and Parts For High-Temperature Service
A197 Standard Specification for Cupola Malleable Iron
A200 Standard Specification for Seamless Intermediate Alloy-Steel Still Tubes for Refinery Service
A202 Standard Specification for Pressure Vessel Plates, Alloy Steel, Chromiummanganese-Silicon
A203 Standard Specification for Pressure Vessel Plates, Alloy Steel, Nickel
A204 Standard Specification for Pressure Vessel Plates, Alloy Steel, Molybdenum
A213 Standard Specification for Seamless Ferritic and Austenitic Alloy-Steel Boiler, Superheater, and Heat- Exchanger Tubes
A214 Standard Specification for Electric-Resistance-Welded Carbon Steel Heat-Exchanger and Condenser Tubes
A216 Standard Specification for Steel Castings, Carbon, Suitable For Fusion Welding For High-Temperature Service
A217 Standard Specification for Steel Castings, Martensitic Stainless and Alloy, For Pressure-Containing Parts Suitable For High-Temperature Service
A234 Standard Specification for Piping Fittings Of Wrought Carbon Steel and Alloy Steel For Moderate and Elevated Temperatures
A240 Standard Specification for Heat-Resisting Chromium and Chromium-Nickel Stainless Steel Plate, Sheet and Strip For Pressure Vessels
A249 Standard Specification for Welded Austenitic Steel Boiler, Superheater, Heat-Exchanger, and Condenser Tubes
A268 Standard Specification for Seamless and Welded Ferritic Stainless Steel Tubing For General Service
A269 Standard Specification for Seamless and Welded Austenitic Stainless Steel Tubing For General Service
A270 Standard Specification for Seamless and Welded Austenitic Stainless Steel Sanitary Tubing
A271 Standard Specification for Seamless austenitic Chromium-Nickel Steel Still Tubes for Refinery Service
A278 Standard Specification for Gray Iron Castings For Pressure-Containing Parts For Temperatures Up To 650°F
A283 Standard Specification for Low and Intermediate Tensile Strength Carbon Steel Plates, Shapes and Bars
A285 Standard Specification for Pressure Vessel Plates, Carbon Steel, Low- and Intermediate-Tensile Strength
A299 Standard Specification for Pressure Vessel Plates, Carbon Steel, Manganese-Silicon
A302 Standard Specification for Pressure Vessel Plates, Alloy Steel, Manganese Molybdenum and Manganese-Molybdenum-Nickel
A312 Standard Specification for Seamless and Welded Austenitic Stainless Steel Pipe
A333 Standard Specification for Seamless and Welded Steel Pipe For Low-Temperature Service
A334 Standard Specification for Seamless and Welded Carbon and Alloy-Steel Tubes For Low-Temperature Service
A335 Standard Specification for Seamless Ferritic Alloy Steel Pipe For High-Temperature Service
A350 Standard Specification for Forgings, Carbon and Low-Alloy Steel Requiring Notch Toughness Testing For Piping Components
A351 Standard Specification for Steel Castings, Austenitic, Austenitic-Ferritic (Duplex) For Pressure-Containing Parts
A352 Standard Specification for Steel Castings, Ferritic and Martensitic, For Pressure Containing Parts Suitable For Low-Temperature Service
A353 Standard Specification for Pressure Vessel Plates, Alloy Steel, 9% Nickel, Double Normalized and Tempered
A358 Standard Specification for Electric-Fusion-Welded Austenitic Chromium-Nickel Alloy Steel Pipe For High-Temperature Service
A369 Standard Specification for Carbon Steel and Ferritic Alloy Steel Forged and Bored Pipe For High-Temperature Service
A376 Standard Specification for Seamless Austenitic Steel Pipe For High-Temperature Central-Station Service
A381 Standard Specification for Metal-Arc-Welded Steel Pipe For Use With High-Pressure Transmission Systems
A387 Standard Specification for Pressure Vessel Plates, Alloy Steel, Chromium molybdenum
A395 Standard Specification for Ferritic Ductile Iron Pressure-Retaining Castings For Use At Elevated Temperatures
A403 Standard Specification for Wrought Austenitic Stainless Steel Piping Fittings
A409 Standard Specification for Welded Large Diameter Austenitic Steel Pipe For Corrosive Or High-Temperature Service
A420 Standard Specification for Piping Fittings Of Wrought Carbon Steel and Alloy Steel For Low-Temperature Service
A426 Standard Specification for Centrifugally Cast Ferritic Alloy Steel Pipe For High Temperature Service
A451 Standard Specification for Centrifugally Cast Austenitic Steel Pipe For High Temperature Service
A479 Standard Specification for Stainless and Heat-Resisting Steel Bars and Shapes For Use In Boilers and Other Pressure Vessels
A487 Standard Specification for Steel Castings Suitable For High-Pressure Service
A494 Standard Specification for Castings, Nickel and Nickel Alloy
A498 Standard Specification for Seamless and Welded Carbon, Ferritic, and Austenitic Alloy Steel Heat-Exchanger Tubes with Integral Fins
A511 Standard Specification for Seamless Stainless Steel Mechanical Tubing
A515 Standard Specification for Pressure Vessel Plates, Carbon Steel, For Intermediate and Higher-Temperature Service
A516 Standard Specification for Pressure Vessel Plates, Carbon Steel, For Moderate- and Lower-Temperature Service
A524 Standard Specification for Seamless Carbon Steel Pipe For Atmospheric and Lower Temperatures
A537 Standard Specification for Pressure Vessel Plates, Heat-Treated, Carbon Manganese-Silicon Steel
A553 Standard Specification for Pressure Vessel Plates, Alloy Steel, Quenched and Tempered 8 and 9% Nickel
A554 Standard Specification for Welded Stainless Steel Mechanical Tubing
A570 Standard Specification for Hot-Rolled Carbon Steel Sheet and Strip, Structural Quality
A571 Standard Specification for Austenitic Ductile Iron Castings For Pressure-Containing Parts Suitable For Low-Temperature Service
A587 Standard Specification for Electric-Welded Low-Carbon Steel Pipe For The Chemical Industry
A632 Standard Specification for Seamless and Welded Austenitic Stainless Steel Tubing (Small-Diameter) for General Service
A645 Standard Specification for Pressure Vessel Plates, 5% Nickel Alloy Steel, Specially Heat Treated
A671 Standard Specification for Electric-Fusion-Welded Steel Pipe For Atmospheric and Lower Temperatures
A672 Standard Specification for Electric-Fusion-Welded Steel Pipe For High-Pressure Service At Moderate Temperatures
A688 Standard Specification for Welded Austenitic Stainless Steel Feedwater Heater Tubes
A691 Standard Specification for Carbon and Alloy Steel Pipe, Electric Fusion-Welded For High-Pressure Service At High Temperatures
A778 Standard Specification for Welded, Unannealed Austenitic Stainless Steel Tubular Products
A789 Standard Specification for Seamless and Welded Ferritic Austenitic Stainless Steel Tubing For General Service
A790 Standard Specification for Seamless and Welded Ferritic Austenitic Stainless Steel Pipe
A803 Standard Specification for Welded Ferritic Stainless Steel Feedwater Heater Tubes
A813 Standard Specification for Single- or Double-Welded Austenitic Stainless Steel Pipe
A814 Standard Specification for Cold-Worked Welded Austenitic Stainless Steel Pipe
A815 Standard Specification for Wrought Ferritic, Ferritic Austenitic and Martensitic Stainless Steel Fittings
A851 Standard Specification for High-Frequency Induction Welded, Unannealed, Austenitic Steel Condenser Tubes
A928 Standard Specification for Ferritic/Austenitic (Duplex) Stainless Steel Pipe Electric Fusion Welded with Addition of Filler Metal

List of ASTM Codes for Piping Materials - Non-Ferrous Materials

B21 Standard Specification for Naval Brass Rod, Bar, and Shapes
B26 Standard Specification for Aluminum-Alloy Sand Castings
B42 Standard Specification for Seamless Copper Pipe, Standard Sizes
B43 Standard Specification for Seamless Red Brass Pipe, Standard Sizes
B61 Standard Specification for Steam or Valve Bronze Castings
B62 Standard Specification for Composition Bronze or Ounce Metal Castings
B68 Standard Specification for Seamless Copper Tube, Bright Annealed
B75 Standard Specification for Seamless Copper Tube
B88 Standard Specification for Seamless Copper Water Tube
B96 Standard Specification for Copper-Silicon Alloy Plate, Sheet, Strip, and Rolled Bar For General Purposes and Pressure Vessels
B98 Standard Specification for Copper-Silicon Alloy Rod, Bar, and Shapes
B127 Standard Specification for Nickel-Copper Alloy (UNS N04400) Plate, Sheet, and Strip
B133 Standard Specification for Copper Rod, Bar, and Shapes
B148 Standard Specification for Aluminum-Bronze Castings
B150 Standard Specification for Aluminum-Bronze Rod, Bar, and Shapes
B152 Standard Specification for Copper Sheet, Strip, Plate, and Rolled Bar
B160 Standard Specification for Nickel Rod and Bar
B161 Standard Specification for Nickel Seamless Pipe and Tube
B162 Standard Specification for Nickel Plate, Sheet, and Strip
B164 Standard Specification for Nickel-Copper Alloy Rod, Bar, and Wire
B165 Standard Specification for Nickel-Copper Alloy (UNS N04400) Seamless Pipe and Tube
B166 Standard Specification for Nickel-Chromium-Iron Alloy (UNS N06600) Rod, Bar, and Wire
B167 Standard Specification for Nickel-Chromium-Iron Alloy (UNS N06600-N06690) Seamless Pipe and Tube
B168 Standard Specification for Nickel-Chromium-Iron Alloy (UNS N06600-N06690) Plate, Sheet, and Strip
B169 Standard Specification for Aluminum Bronze Plate, Sheet, Strip, and Rolled Bar
B171 Standard Specification for Copper-Alloy Condenser Tube Plates
B187 Standard Specification for Copper Bar, Bus Bar, Rod, and Shapes
B209 Standard Specification for Aluminum and Aluminum-Alloy Sheet and Plate
B210 Standard Specification for Aluminum-Alloy Drawn Seamless Tubes
B211 Standard Specification for Aluminum-Alloy Bars, Rods, and Wire
B221 Standard Specification for Aluminum-Alloy Extruded Bars, Rods, Wire, Shapes, and Tubes
B241 Standard Specification for Aluminum-Alloy Seamless Pipe and Seamless Extruded Tube
B247 Standard Specification for Aluminum-Alloy Die, Hand, and Rolled Ring Forgings
B280 Standard Specification for Seamless Copper Tube For Air Conditioning and Refrigeration Fluid Service
B283 Standard Specification for Copper and Copper-Alloy Die Forgings (Hot-Pressed)
B265 Standard Specification for Titanium and Titanium Alloy Strip, Sheet, and Plate
B333 Standard Specification for Nickel-Molybdenum Alloy Plate, Sheet, and Strip
B335 Standard Specification for Nickel-Molybdenum Alloy Rod
B337 Standard Specification for Seamless and Welded Titanium and Titanium Alloy Pipe
B345 Standard Specification for Aluminum-Alloy Seamless Extruded Tube and Seamless Pipe For Gas and Oil Transmission and Distribution Piping Systems
B361 Standard Specification for Factory-Made Wrought Aluminum and Aluminum Alloy Welding Fittings
B366 Standard Specification for Factory-Made Wrought Nickel and Nickel-Alloy Welding Fittings
B381 Standard Specification for Titanium and Titanium Alloy Forgings
B407 Standard Specification for Nickel-Iron-Chromium Alloy Seamless Pipe and Tube
B409 Standard Specification for Nickel-Iron-Chromium Alloy Plate, Sheet, and Strip
B423 Standard Specification for Nickel-Iron-Chromium-Molybdenum-Copper Alloy (UNS No8825 and N08221) Seamless Pipe and Tube
B424 Standard Specification for Nickel-Iron-Chromium-Molybdenum-Copper Alloy (UNS No8825 and N08221) Plate, Sheet, and Strip
B425 Standard Specification for Nickel-Iron-Chromium-Molybdenum-Copper Alloy (UNS No8825 and N08221) Rod and Bar
B435 Standard Specification for UNS N06002, UNS N06230, UNS N12160, and UNS R30556 Plate, Sheet, and Strip
B443 Standard Specification for Nickel-Chromium-Molybdenum-Columbium Alloy (UNS N06625) Plate, Sheet, and Strip
B444 Standard Specification for Nickel-Chromium-Molybdenum-Columbium Alloy (UNS N06625) Seamless Pipe and Tube
B446 Standard Specification for Nickel-Chromium-Molybdenum-Columbium Alloy (UNS N06625) Rod and Bar
B462 Standard Specification for Forged or Rolled UNS N06030, UNS N06022, UNS N06035, UNS N06200, UNS N06059, UNS N10362, UNS N06686, UNS N08020, UNS N08367, UNS N10276, UNS N10665, UNS N10675, UNS N10629, UNS N08031, UNS N06045, UNS N06025, UNS R20033 Alloy Pipe Flanges, Forged Fittings, and Valves and Parts for Corrosive High-Temperature Service
B463 Standard Specification for UNS N08020 Alloy Plate, Sheet, and Strip
B464 Standard Specification for Welded Chromium-Nickel-Iron-Molybdenum-Coppercolumbium Stabilized Alloy (UNS N08020) Pipe
B466 Standard Specification for Seamless Copper-Nickel Pipe and Tube
B467 Standard Specification for Welded Copper-Nickel Pipe
B491 Standard Specification for Aluminum and Aluminum Alloy Extruded Round Tubes For General-Purpose Applications
B493 Standard Specification for Zirconium and Zirconium Alloy Forgings
B514 Standard Specification for Welded Nickel-Iron-Chromium Alloy Pipe
B517 Standard Specification for Welded Nickel-Chromium-Iron-Alloy (UNS N06600, UNS N06603, UNS N06025, and UNS N06045) Pipe
B523 Standard Specification for Seamless and Welded Zirconium and Zirconium Alloy Tubes
B547 Standard Specification for Aluminum and Aluminum-Alloy Formed and Arc-Welded Round Tube
B550 Standard Specification for Zirconium and Zirconium Alloy Bar and Wire
B551 Standard Specification for Zirconium and Zirconium Alloy Strip, Sheet, and Plate
B564 Standard Specification for Nickel Alloy Forgings
B575 Standard Specification for Low-Carbon Nickel-Molybdenum-Chromium Alloy Plate, Sheet, and Strip
B581 Standard Specification for Nickel-Chromium-Iron-Molybdenum-Copper Alloy Rod
B582 Standard Specification for Nickel-Chromium-Iron-Molybdenum-Copper Alloy Plate, Sheet, and Strip
B584 Standard Specification for Copper Alloy Sand Castings For General Applications
B619 Standard Specification for Welded Nickel and Nickel-Cobalt Alloy Pipe
B620 Standard Specification for Nickel-Iron-Chromium-Molybdenum Alloy (UNS N08320) Plate, Sheet, and Strip
B621 Standard Specification for Nickel-Iron-Chromium-Molybdenum Alloy (UNS N08320) Rod
B622 Standard Specification for Seamless Nickel and Nickel-Cobalt Alloy Pipe and Tube
B625 Standard Specification for Nickel Alloy Plate and Sheet
B649 Standard Specification for Ni-Fe-Cr-Mo-Cu-N Low-Carbon Alloys (UNS N08925, UNS N08031, UNS N08034, UNS N08354, and UNS N08926), and Cr-Ni-Fe-N Low-Carbon Alloy (UNS R20033) Bar and Wire, and Ni-Cr-Fe-Mo-N Alloy (UNS N08936) Wire
B658 Standard Specification for Zirconium and Zirconium Alloy Seamless and Welded Pipe
B675 Standard Specification for UNS No8366 and UNS No8367 Welded Pipe
B688 Standard Specification for Chromium-Nickel-Molybdenum-Iron (UNS No8366 and UNS N08367) Plate, Sheet, and Strip
B690 Standard Specification for Iron-Nickel-Chromium-Molybdenum Alloys (UNS No8366 and UNS N08367) Seamless Pipe and Tube
B705 Standard Specification for Nickel-Alloy (UNS No6625 and N08825) Welded Pipe
B725 Standard Specification for Welded Nickel (UNS N02200Kjns N02201) and Nickel Copper Alloy (UNS N04400) Pipe
B729 Standard Specification for Seamless UNS N08020, UNS N08026, and UNS N08024 Nickel-Alloy Pipe and Tube
B804 Standard Specification for UNS No8367 Welded Pipe